Processing of Semiconductors Using Vaporized Solvents

ABSTRACT

Processes and apparatuses for the treatment of semiconductor workpieces are provided. In some embodiments, a method can include placing the workpiece into a process chamber; vaporizing a solvent to create a vaporized solvent; introducing the vaporized solvent into the process chamber; and exposing the workpiece to the vaporized solvent.

PRIORITY CLAIM

The present application is based on and claims priority to U.S.Provisional Application No. 62/599,105, having a filing date of Dec. 15,2017, which is incorporated by reference herein.

FIELD

The present disclosure relates generally to treatment of a workpieceusing vaporized solvents.

BACKGROUND

Post-implantation photoresist removal and post-etch residue removal havebeen traditionally accomplished using an oxygen-containing plasma drystrip. However, the resultant silicon (Si) or silicon-germanium (SiGe)loss from the oxidizing chemistry can cause degradation of deviceperformance, and the interaction of oxygen radicals with low-k films cancause low-k damage. Strip processes based on reducing chemistries (e.g.hydrogen and nitrogen) generally result in lower substrate loss.However, these types of processes do not completely resolve the materialloss issue while also introducing additional problems. For example,hydrogen-based processes have low resist removal rates and hydrogenplasma can also cause device shifts due to vacancy formation deep insidethe Si and SiGe substrates. Therefore, there is a need for newchemistries to be introduced into the dry strip process to meetincreasing product performance requirements.

SUMMARY

Aspects and advantages of embodiments of the present disclosure will beset forth in part in the following description, or may be learned fromthe description, or may be learned through practice of the embodiments.

One example aspect of the present disclosure is directed to a method forprocessing a workpiece. The method can include placing the workpieceinto a process chamber. The method can include vaporizing a solvent tocreate a vaporized solvent. The method can include introducing thevaporized solvent into the process chamber. The method can includeexposing the workpiece to the vaporized solvent.

Other example aspects of the present disclosure are directed to systems,methods, and apparatuses for processing of workpieces.

These and other features, aspects and advantages of various embodimentswill become better understood with reference to the followingdescription and appended claims. The accompanying drawings, which areincorporated in and constitute a part of this specification, illustrateembodiments of the present disclosure and, together with thedescription, serve to explain the related principles.

BRIEF DESCRIPTION OF THE DRAWINGS

Detailed discussion of embodiments directed to one of ordinary skill inthe art are set forth in the specification, which makes reference to theappended figures, in which:

FIG. 1 depicts a semiconductor workpiece processing apparatus accordingto example embodiments of the present disclosure;

FIG. 2 depicts a flow diagram of a method according to exampleembodiments of the present disclosure;

FIG. 3 depicts a flow diagram of a method according to exampleembodiments of the present disclosure;

FIG. 4 depicts a semiconductor workpiece processing apparatus accordingto example embodiments of the present disclosure;

FIG. 5 depicts a semiconductor workpiece processing apparatus accordingto example embodiments of the present disclosure;

FIG. 6 depicts a semiconductor workpiece processing apparatus accordingto example embodiments of the present disclosure;

FIG. 7 depicts a semiconductor workpiece processing apparatus accordingto example embodiments of the present disclosure;

FIG. 8 depicts an example separation grid according to exampleembodiments of the present disclosure; and

FIG. 9 depicts a semiconductor workpiece processing apparatus accordingto example embodiments of the present disclosure.

DETAILED DESCRIPTION

Reference now will be made in detail to embodiments, one or moreexamples of which are illustrated in the drawings. Each example isprovided by way of explanation of the embodiments, not limitation of thepresent disclosure. In fact, it will be apparent to those skilled in theart that various modifications and variations can be made to theembodiments without departing from the scope or spirit of the presentdisclosure. For instance, features illustrated or described as part ofone embodiment can be used with another embodiment to yield a stillfurther embodiment. Thus, it is intended that aspects of the presentdisclosure cover such modifications and variations.

Example aspects of the present disclosure are directed to semiconductorworkpiece processing. More specifically, in some embodiments, exampleaspects of the present disclosure are directed toward workpiece surfacecleaning, such as post-implantation photoresist and post-etch residueremoval. The processes and apparatuses discussed herein can be used inboth front-end-of-line and back-end-of-line applications.

Embodiments can include a non-oxidizing dry-strip process that usesinjecting of solvent chemicals into a process chamber to facilitatephotoresist and post-etch residue removal. Embodiments can performeffective photoresist strip and residue removal with reduced surfacedamage and oxidation. The workpieces (e.g., Si and SiGe wafers) can beexposed to the chemical vapor of the solvent. The vaporized solvent canattack photoresist and post-etch residues on the workpiece surface.Furthermore, in some embodiments, a plasma can be generated and appliedin combination with solvent vapor. The workpiece can then be exposed toradicals generated in the plasma which can assist in workpiece cleaning.

Example aspects of the present disclosure are discussed with referenceto treating a semiconductor wafer workpiece for purposes of illustrationand discussion. Those of ordinary skill in the art, using thedisclosures provided herein, will understand that aspects of the presentdisclosure can be used in conjunction with the processing of otherworkpieces without deviating from the scope of the present disclosure.As used herein, the use of the term “about” in conjunction with anumerical value can refer to within 20% of the stated numerical value.

FIG. 1 depicts a semiconductor workpiece processing apparatus 100according to example embodiments of the present disclosure. A solventstorage receptacle 103 containing a solvent is positioned upstream ofthe process chamber 110 and has a solvent feed gas line 101.

The solvent storage receptacle 103 can be in the form of a liquid tank.The solvent feed gas line 101 can introduce a carrier gas to the solventstorage receptacle 103. The carrier gas can be inert (e.g., noble gas,nitrogen, etc.) or can otherwise be chemically active in the process.

The solvent feed gas line 101 can supply pressure to the solvent storagereceptacle 103 to drive the solvent forward in the process through thesolvent storage receptacle outlet line 119. Alternatively (or inconjunction), a solvent pump 121 can be provided on the solvent storagereceptacle outlet line 119 to pull solvent from the solvent storagereceptacle 103 and push the solvent through the solvent line 120 to thevaporizer 105. The solvent pump 121 (e.g., a positive displacement pump)can also serve to control the mass flow rate of solvent being sent tothe vaporizer 105. A mass flow meter (MFM) 106 and/or a volumetric flowmeter (not shown) can be provided on the solvent line 120. The mass flowmeter 106 and/or volumetric flow meter can be located before or afterthe vaporizer 105 and can send information to a controller (not shown)to control the amount of solvent sent to the process chamber 110.

The controller can be any suitable control device for controllingoperation of the system. For instance, the controller can include one ormore processors and one or more memory devices. The one or more memorydevices can store computer-readable instructions that when executed bythe one or more processors cause the one or more processors to performoperations. The operations can include controlling flow of the solventbased on signals from the mass flow meter and/or volumetric flow meter.The vaporizer 105 can serve to vaporize liquid solvent coming from thesolvent storage receptacle 103 and deliver the vaporized solventdownstream to the plasma chamber 111 and/or the process chamber 110 viathe solvent line 120.

A purge gas line 102 can be connected to the solvent line 120 to, forexample, purge out residue liquids in the solvent line 120 during systemmaintenance. A drain line 140 can be connected to the solvent line 120for cleaning and maintenance of the processing apparatus 100.Furthermore, a bypass line 107 can be connected to the solvent line 120such that the solvent bypasses the plasma chamber 111 and processchamber 110. The bypass line 107 can be particularly useful forobtaining the correct flow rate and composition in the solvent line 120prior to administering the contents of the solvent line 120 to theplasma chamber 111 and the process chamber 110. The bypass line 107 canfeed directly into the process chamber evacuation pump 118 where it canbe discarded or recycled. The main function of the process chamberevacuation pump 118 is controlled removal of gasses (including solvent)from the process chamber 110. However, the process chamber evacuationpump 118 can also be used to clear the various gas lines of theprocessing apparatus 100.

The processing apparatus 100 can include various feed gas lines 108 anda gas box 109 where the gasses can be mixed and conditioned (e.g., withheating or cooling; i.e., the gas box can include heating and coolingelements, although not shown). The vaporized solvent (and optionally acarrier gas) can be delivered directly to the gas box 109 (as in FIG. 8)or can be delivered to the gas box outlet 122, where it can mix withother gasses coming from the gas box 109. As shown in FIG. 1, thevaporized solvent or a mixture of the vaporized solvent and other gasesfrom the gas box 109 enters the process chamber 110 through a plasmachamber 111.

The plasma chamber 111 can include an RF plasma source 112. The RFplasma source 112 can be coupled to an inductive element to generate aninductively coupled plasma in the plasma chamber 111. A plasma canoptionally be ignited in the plasma chamber 111 by turning on the RFplasma source 112. When the RF plasma source 112 is turned on, thevaporized solvent molecules can dissociate in the plasma and produceactive species that assist in treating the surface of the workpiece 116(e.g., a semiconductor wafer). The plasma chamber 111 can be separatedfrom the process chamber 110 via a separation grid 113.

The resultant gas stream including the vaporized solvent and potentiallyother gasses exits the plasma chamber 111 and enters the process chamber110. The process chamber 110 can include a seat or pedestal 114 forholding a workpiece 116. The process chamber 110 can also have multiplepedestals 114 for holding multiple workpieces 116, or a single pedestal114 that can support multiple workpieces 116, as shown in FIG. 1. Thegas stream exiting the plasma chamber 111 can pass through a separationgrid 113 and enter the process chamber 110 where the workpiece 116 isplaced. The separation grid 113 can serve to redistribute the gas flowevenly over the surface of the workpiece 116 and also filter out chargedions generated in the plasma. Therefore, the separation grid 113 cankeep charged ions out of the process chamber 110 and allow neutralradicals generated in a plasma to pass through.

The workpiece 116 in the process chamber can then be exposed to aneutral radical stream that cleans the workpiece surface, attacksphotoresist, and removes post-etch residues. Alternatively, the RFplasma source 112 can remain off In this case, the workpiece(s) can beexposed to the vaporized solvent, or a mixture of the vaporized solventand other gasses. The surface of the workpiece 116 can be cleaned via achemical reaction that occurs between the vaporized solvent and theworkpiece surface. That is, the vaporized solvent can react withphotoresists and etch residues, or other films or substances on thesurface of the workpiece 116.

FIG. 2 depicts a flow diagram of a method according to exampleembodiments of the present disclosure. The method will be described withreference to the apparatus embodiment of FIG. 1. FIG. 2 depicts stepsperformed in a particular order for purposes of illustration anddiscussion. Those of ordinary skill in the art, using the disclosuresprovided herein, will understand that various steps of any of themethods disclosed herein can be adapted, expanded, rearranged, omitted,performed simultaneously, and/or modified in various ways withoutdeviating from the scope of the present disclosure.

The method begins with the initiation of liquid solvent flow to thevaporizer 105 and setting the desired flow rate (201). The desired flowrate can be achieved using the solvent pump 121, the mass or volumetricflow meter 106, and a controller. At this time, the vaporized solventcan be discharged to the bypass line 107. After the desired flow ratehas been achieved, or the flow rate has reached the desired steady stateconditions, the bypass line 107 can be closed and the solvent vapor flowcan proceed to the process chamber (202). The solvent vapor (or amixture of the vapor and other gasses) can continue filling the processchamber 110 until the pressure stabilizes at the desired chamberpressure (203). The desired pressure can be obtained using a pressuregauge in the process chamber or plasma chamber in combination with apressure controller (not shown). The workpiece 116 (e.g. wafer) can thenbe exposed to the chemical vapor for a predetermined period of time(204). After the exposure of the workpiece to the solvent vapor iscomplete, solvent liquid flow to the vaporizer 105 can turned off andthe solvent vapor flow to the process chamber 110 correspondingly stops(205). The residue chemicals and the remaining gasses in the processchamber 110 can then be evacuated by the process chamber evacuation pump118.

FIG. 3 depicts a flow diagram of a method according to exampleembodiments of the present disclosure. The method will be described withreference to the apparatus embodiment of FIG. 1. FIG. 3 depicts stepsperformed in a particular order for purposes of illustration anddiscussion. Those of ordinary skill in the art, using the disclosuresprovided herein, will understand that various steps of any of themethods disclosed herein can be adapted, expanded, rearranged, omitted,performed simultaneously, and/or modified in various ways withoutdeviating from the scope of the present disclosure.

The method begins with the initiation of liquid solvent flow to thevaporizer 105 and setting the desired flow rate (301). To initialize thesystem, the vaporized solvent can first be discharged to the bypass line107. After the desired flow rate has been achieved, or the flow rate hasreached the desired steady state, the bypass line 107 can be closed andthe solvent vapor flow can proceed to the process chamber (302). Thesolvent vapor (or a mixture of the vapor and other gasses) can continuefilling the process chamber 110 until the pressure stabilizes at thedesired chamber pressure (303). The workpiece 116 (e.g. wafer) can thenbe exposed to the chemical vapor for a predetermined period of time(304). Next, the RF source 112 can be engaged to strike plasma in theplasma chamber 111, or the region above the separation grid 113 (305).The workpiece can then be exposed to the radicals created by the plasmafor a predetermined amount of time (306). Alternatively, the RF source112 can be engaged at an earlier time while the solvent is filling theplasma chamber 111 and the process chamber 110 (step not shown). Thisalternative process step can induce a greater number of solvent radicalsin the process chamber 110. Finally, after the workpiece processing, theRF source 112 and solvent vapor flow can be stopped and the processchamber evacuated (307).

FIG. 4 illustrates a processing apparatus 400 according to exampleembodiments of the present disclosure. The solvent gas feed line 101 isshown carrying a feed gas through a mass flow controller 117 and to asolvent gas inlet line 124. The rate of feed gas delivered can beadjusted and maintained using the mass flow controller 117. A solventstorage receptacle bypass valve 123 can be included for bypassing feedgas around the solvent storage receptacle 103.

In the embodiment of FIG. 4, the solvent storage receptacle 103 is anampoule that holds a metered quantity of liquid solvent. The solvent gasinlet line 124 can include a bubbler 115 that disperses the feed gaswithin the liquid solvent, effectively saturating the feed gas withsolvent vapors. The solvent storage receptacle outlet line 119 can beabove the liquid level inside the solvent storage receptacle 103 suchthat only solvent vapor (and potentially feed gas) can continue down thesolvent line 120. The amount of solvent vapor that is fed into thesolvent feed line 120 can also be controlled by adjusting the solventvapor pressure using a solvent temperature control component 125. Thesolvent temperature control component 125 can be a coil that functionsas a heating and cooling element, allowing for both raising and loweringthe temperature of the solvent. Bidirectional solvent temperaturecontrol allows for precise control of the solvent vapor pressure, whichis of primary importance in controlling the amount of solvent vaporbeing delivered downstream. Otherwise, the processing apparatus of FIG.4 can operate in much the same manner, and assume alternativeconfigurations, as the other processing apparatuses discussed herein.

FIG. 5 illustrates an example processing apparatus 500 according toexample embodiments the present disclosure. The processing apparatus 500includes an ampoule (i.e., a solvent storage receptacle) 103 thatcontains a liquid solvent. The ampoule 103 maintains the liquid solventat a preset temperature. The temperature can be maintained using asolvent temperature control component 125. The solvent temperaturecontrol component 125 can be in the form of a coil that conveys a fluidthat heats or cools the liquid solvent. Instead of a coil, the solventtemperature control component 125 can be in the form of a shell orjacket that encompasses the solvent storage receptacle 103. Thetemperature control component can also include a temperature measurementdevice (e.g., a thermometer or thermocouple) in combination with atemperature controller. In the configuration of FIG. 5, the solventstorage receptacle outlet line 119 is above the solvent liquid level ofthe solvent ampoule 103. Therefore, the primary means of conveyingvaporized solvent to the process chamber 110 is evaporation from thesurface of the liquid solvent.

FIG. 6 illustrates an example processing apparatus 600 according toexample embodiments of the present disclosure. The processing apparatus600 does not have a feed gas line integrated within the solvent storagereceptacle 103. The solvent storage receptacle can maintain the liquidsolvent at a present temperature using a heating and cooling system 125.The temperature of the liquid solvent can then determine the pressurewithin the solvent storage receptacle 103, and the temperature can beraised if more solvent flow is desired. A mass or volumetric flow meter106, a controller, and a control valve can be located on the solventline 120 to control the solvent flow rate. The mass or volumetric flowmeter 106 can therefore control the amount and rate of vaporized solventgoing to the plasma chamber 111 and process chamber 120. The purge gasline 102 can be used to clean out the solvent line 120 and bypass line107, for example, during system maintenance.

FIG. 7 illustrates an example processing apparatus 700 according toexample embodiments the present disclosure. In the example of FIG. 7,the solvent line 120 discharges directly into the process chamber andbypasses the gas box 109, plasma chamber 111, RF source 112, and theseparation grid 113.

In some embodiments, the solvent line 120 can be configured to dischargeinto the process chamber via post-plasma injection in a multi-plateseparation grid 113. For instance, FIG. 8 depicts a multi-plateseparation grid 113 including a first grid plate 113.2 and a second gridplate 113.4 disposed in parallel relationship for UV/ion filtering.

The first grid plate 113.2 and a second grid plate 113.4 can be inparallel relationship with one another. The first grid plate 113.2 canhave a first grid pattern having a plurality of holes. The second gridplate 113.4 can have a second grid pattern having a plurality of holes.The first grid pattern can be the same as or different from the secondgrid pattern. Charged particles (e.g., ions) can recombine on the wallsin their path through the holes of each grid plate 113.2, 113.4 in theseparation grid 113. Neutral species (e.g., radicals) can flowrelatively freely through the holes in the first grid plate 113.2 andthe second grid plate 113.4.

Subsequent to the second grid plate 113.2, the solvent line 120 can beconfigured to admit vaporized solvent into the particles flowing throughthe separation grid 113. The vaporized solvent and/or particles (e.g.,neutral radicals) can pass through a third grid plate 113.6 into theprocess chamber 110. More or fewer grid plates can be used withoutdeviating from the scope of the present disclosure. In addition, thesolvent line 120 can be configured to admit vaporized solvent into theseparation grid 113 at a location below the separation grid 113.

FIG. 9 illustrates an example processing apparatus 800 according toexample embodiments of the present disclosure. In FIG. 9, the solventline 120 has a controller and two control valves 126 that can routevaporized solvent (and potentially carrier gasses) directly into theprocess chamber 110, or upstream of the process chamber (e.g., into thegas box 109, as shown), or a combination of both. That is, the solventline 120 can discharge into the process chamber 110 as well as into thegas box 109, gas box outlet 122, and the plasma chamber 111. Theproportion of solvent (and optionally carrier gas) being sent to each ofthe process chamber 110, the gas box 109, the gas box outlet 122, andthe plasma chamber 111 can therefore all be adjusted independently. Thatis, the solvent line 120 can have lines and flow control mechanisms(e.g., a controller, a control valve, and a mass/volume flow meter) tometer solvent as well as a carrier gas to any combination of the processchamber 110, the gas box 109, the gas box outlet 122, and the plasmachamber 111. The discharge configurations of FIGS. 7 and 8 can beadapted to any of the embodiments discussed herein.

Embodiments of the present disclosure include processing methods,specifically applicable to semiconductor workpieces, such assemiconductor wafers. The methods can include placing the workpiece intoa process chamber 110, vaporizing a solvent and feeding the vaporizedsolvent into the process chamber 110, and exposing the workpiece to thevaporized solvent. Non-limiting examples of solvents that can be appliedinclude isopropyl alcohol (IPA), acetone, methanol,N-methyl-2-pyrrolidone (NMP), N-ethyl-2-pyrrolidone (NEP), dimethylsulfoxide (DMSO), propylene glycol methyl ether acetate (PGMEA), methylethyl ketone (MEK), n-Butyl acetate (NBA), y-butyrolactone (GBL),propylene carbonate (PC), triethylamine (TEA), and acetonitrile.Furthermore, mixtures of solvents can also be applied and the solventscan be applied at various pressures and partial pressures.

Different solvents and mixtures of solvents can also be applied inseries. For example, a workpiece can be exposed to a first solvent (orsolvent mixture) for a first period followed by a second solvent for asecond period. The workpiece can then be exposed to a third solvent (orsolvent mixture) for a third period, and so on. Furthermore, theworkpiece can be exposed to each solvent or solvent mixture with orwithout incorporating a plasma using an RF source 112.

The solvent can be carried to the process chamber 110 using one or morecarrier gasses. The carrier gas can be an inert feed gas (e.g., noblegasses, etc.) or one or more of the carrier gasses can be active in theprocess chemistry by synergizing with the solvent or other processgasses emanating from the gas box 109. Specific examples of inter and/orcarrier gases include helium, nitrogen, and/or argon.

The solvent can be put in gaseous form by feeding liquid solvent to avaporizer 105. The amount of solvent fed to the process chamber 110 canbe controlled using metering pumps 121, mass flow meters 106 (e.g., onthe feed gas line 101 or solvent line 120), volumetric flow meters(e.g., on the feed gas line 101 or solvent line 120), logic controllers,control valves, and pressure gauges, as well as combinations thereof.Prior to feeding the solvent to the process chamber 120, the solventflow rates can be stabilized or brought to steady state using a bypassline 107. After the solvent flow rate has stabilized, a control valve onthe bypass line 107 can be closed and the solvent routed to the processchamber 110 where it can be exposed to the workpiece 116.

The solvent can be administered to the process chamber in various ways.That is, the solvent line 120 can direct the solvent to variouslocations within the processing apparatus such as the process chamber110, the gas box 109, the gas box outlet 122, and the plasma chamber111. Furthermore, the processing apparatus can incorporate all of theseoptions into a single system and control the amount of solvent sent toeach location using controllers, control valves, and mass and volumetricflow meters. Furthermore, an RF source 112 can be engaged to strike aplasma (with optionally incorporating various gasses from the variousgas feed lines 108) before the solvent is administered, while thesolvent is being administered, or after the solvent has beenadministered but is still residing within the process chamber 110.Engaging the RF source 112 allows for dissociating the vaporized solventinto active species that assist in the process.

The solvent can pass through a separation grid 113 prior to entering theprocess chamber 110. The separation grid 113 can disperse the vaporizedsolvent (and potentially other gasses) as it enters the process chamber110 such that the gasses are evenly exposed to the workpiece 116. Whenthe RF source 112 is engaged, the separation grid 113 can capturecharged ions, allowing only neutral radicals to pass through to theprocess chamber 110 and keeping charged radicals out.

Methods can include exposing the workpiece 116 to a plasma-affectedvaporized solvent (i.e., a vaporized solvent that has been exposed to aplasma and/or has been ignited by an RF source) and exposing theworkpiece 116 to a non-plasma-affected vaporized solvent (i.e., avaporized solvent that has not been exposed to a plasma and has not beenignited by an RF source). The method can also be reversed. That is, theworkpiece 116 can be exposed to a non-plasma-affected vaporized solventfollowed by a plasma-affected vaporized solvent. The vaporized solventcan also be mixed with one or more other gasses or plasmas (e.g.,hydrogen-, nitrogen-, and/or oxygen-containing plasmas) and then beexposed to the workpiece 116.

The pressure in the process chamber 110 can be held constant or variedwhile the solvent is exposed to the workpiece 116. That is, the pressurein the process chamber 110 can be controlled to rise, fall, or fluctuateover time. Further, the partial pressures of the solvent and othergasses can be controlled.

The liquid solvent in the solvent storage receptacle 103 can be held ata constant temperature. The temperature of the liquid solvent isespecially critical when the solvent vapor pressure is the primary orsole means of conveying solvent to the process chamber 110.

Therefore, the solvent storage receptacle 103 can include a temperaturecontrol component for raising or lowering the temperature of thesolvent. The temperature control component can include a coil 125 inwhich a heating or cooling fluid flows, or the coil 125 can include anelectric heating element. The temperature control component can alsotake the form of a shell that encompasses the solvent storage receptacle103 and contains and electric heating element or temperature controlfluid. The solvent storage receptacle 103 may further have an insulatingjacket to assist in controlling temperature.

The solvent storage receptacle 103 can take multiple forms including ametal or glass liquid tank, or a compressed gas tank. The solventstorage receptacle 103 can also be a metered ampoule that delivers aspecific volume or mass of liquid solvent to the process chamber 110. Anampoule can be particularly useful in situations where the solvent isdelivered downstream by heating and evaporating the liquid solventwithin the solvent storage receptacle 103. The solvent can also bedelivered downstream by dispersing (e.g., using a bubbler 115) a carriergas within the liquid solvent or passing a carrier gas over the liquidsolvent as it evaporates. The amount of solvent delivered can becontrolled in this scenario, at least in part, by measuring and meteringthe flow rate (e.g., using a mass or volumetric flow meter andcontroller 106) of the carrier gas prior to the carrier gas makingcontact with the solvent.

As discussed above, the solvent can be delivered directly to the processchamber 110. Various other gases can also be delivered to the processchamber 110 in combination with the solvent. Furthermore, the solventcan be delivered directly to the process chamber 110 while various othergasses are delivered to the process chamber 110 in plasma form afterpassing through the plasma chamber 111. In addition and/or in thealternative, a fraction of the solvent can be diverted to the processchamber 110 while the remainder of the solvent passes through the plasmachamber 111 and is exposed to the RF source 112.

The process chamber 110 and/or workpiece can be heated while the solventis being exposed to the workpiece 116. For example, the process chamberand/or workpiece can be maintained at a temperature range of from about50° C. to about 400° C.

After the solvent has been exposed to the workpiece 116, the processchamber 110 can be evacuated using the process chamber evacuation pump118. A purge gas can also be used to help empty the process chamber 110.However, the process pump 118 can also be used to maintain a constantpressure within the process chamber 110 as fresh solvent and potentiallyother gasses are introduced to the process chamber 110. The freshsolvent and other gasses can be introduced continuously (at a constantflow rate) or in periodic bursts (e.g., the process chamber is chargedwith fresh solvent every 10 minutes).

Instead of a single plasma chamber, the processing apparatus 100 canhave multiple plasma chambers each having an RF source. For example,FIGS. 1, 4, 5, 6, 7, and 9 show a processing apparatus having dualplasma chambers 111 and dual RF sources 112. This can alloy for greaterprocess efficiency as multiple workpieces can be treated in the processchamber 110 at once, helping to conserve the footprint of the processequipment and improving overall throughout.

While the present subject matter has been described in detail withrespect to specific example embodiments thereof, it will be appreciatedthat those skilled in the art, upon attaining an understanding of theforegoing may readily produce alterations to, variations of, andequivalents to such embodiments. Accordingly, the scope of the presentdisclosure is by way of example rather than by way of limitation, andthe subject disclosure does not preclude inclusion of suchmodifications, variations and/or additions to the present subject matteras would be readily apparent to one of ordinary skill in the art.

1-11. (canceled)
 12. A semiconductor workpiece processing apparatuscomprising: a solvent storage receptacle; a vaporizer configured tovaporize a solvent from the solvent storage receptacle to generate avaporized solvent; a process chamber; a plasma chamber having an RFsource operable to generate a plasma, the plasma chamber being remotefrom the process chamber; and a solvent line that connects the solventstorage receptacle to the process chamber, the solvent line operable tointroduce the vaporized solvent into the process chamber.
 13. Thesemiconductor workpiece processing apparatus of claim 11, wherein thesolvent comprises one or more of one or more of isopropyl alcohol (IPA),acetone, methanol, N-methyl-2-pyrrolidone (NMP), N-ethyl-2-pyrrolidone(NEP), dimethyl sulfoxide (DMSO), propylene glycol methyl ether acetate(PGMEA), methyl ethyl ketone (MEK), n-Butyl acetate (NBA),γ-butyrolactone (GBL), propylene carbonate (PC), triethylamine (TEA),and acetonitrile.
 14. The apparatus of claim 12, wherein the plasmachamber is connected between the solvent line and the process chamber.15. The apparatus of claim 14, further comprising a separation gridseparating the plasma chamber from the process chamber.
 16. Theapparatus of claim 12, further comprising a mass flow meter or avolumetric flow meter on the solvent line.
 17. The apparatus of claim12, wherein the solvent storage receptacle is a liquid tank, acompressed gas tank, or an ampoule.
 18. The apparatus of claim 12,wherein the solvent line feeds directly into the process chamber andbypasses a plasma chamber and a separation grid separating the plasmachamber from the process chamber.
 19. The apparatus of claim 12, whereinthe solvent line feeds directly into a separation grid separating theplasma chamber from the process chamber.
 20. The apparatus of claim 19,wherein the solvent line feeds directly between a plurality of gridplates in the separation grid.